4. DISSOCIATION OF CH-ACIDS

4.1. Aliphatic acids

4.1.1. R¹R²R³CH

4.1.1.1. R¹ = –H, R² = –H, R³ = X

4.1.1.1.1. R¹ = –H, R² = –H, R³ = –H, alkyl, alkenyl

4.1.1.1.2. R¹ = –H, R² = –H, R³ = –C(O)X

4.1.1.1.3. R¹ = –H, R² = –H, R³ = functional group, substituted alkyl or

alkenyl

4.1.1.1.4. R¹ = –H, R² = –H, R³ = phenyl or substituted phenyl

4.1.1.1.5. R¹ = –H, R² = –H, R³ = heterocycle

4.1.1.2. R¹ = –H, R² = alkyl, alkenyl, cycloalkyl, R³ = X

4.1.1.2.1. R¹ = –H, R² = alkyl, R³ = alkyl

4.1.1.2.2. R¹ = –H, R² = alkyl, R³ = –C(O)X

4.1.1.2.3. R¹ = –H, R² = alkyl, alkenyl, cycloalkyl, R³ = –NO₂

4.1.1.2.4. R¹ = –H, R² = alkyl R³ = functional group, (substituted) phenyl,

heterocycle

4.1.1.3. R¹ = –H, R² ,R³ = alkyl substituted by functional group

4.1.1.4. R¹ = –H, R² = functional group, R³ = X

4.1.1.4.1. R¹ = –H, R² = halogen, R³ = functional group, (substituted) phenyl

4.1.1.4.2. R¹ = –H, R² = –C(O)X, R³ = X

4.1.1.4.2.1. R¹ = –H, R² , R³ = –C(O)X

4.1.1.4.2.1.1. XC(O)CH₂C(O)H

4.1.1.4.2.1.2. XC(O)CH₂C(O)Me

4.1.1.4.2.1.3. XC(O)CH₂C(O)X’

4.1.1.4.2.1.4. XC(O)CH₂C(O)OX’

4.1.1.4.2.1.5. XC(O)CH₂C(O)X’ (X’ = substituted alkyl)

4.1.1.4.2.1.6. XC(O)CH₂C(O)X’ (X’ = substituted phenyl)

4.1.1.4.2.1.7. XC(O)CH₂C(O)X’ (X, X’ = heterocycle)

4.1.1.4.2.2. R¹ = –H, R² = –C(O)X, R³ = –C(S)X

4.1.1.4.2.3. R¹ = –H, R² = –C(O)X, R³ = –NO₂

4.1.1.4.2.4. R¹ = –H, R² = –C(O)X, R³ = –SX, S⁺X₂

4.1.1.4.2.5. R¹ = –H, R² = –C(O)X, R³ = –S(O)X

4.1.1.4.2.6. R¹ = –H, R² = –C(O)X, R³ = –SO₂X

4.1.1.4.2.7. R¹ = –H, R² = –C(O)X, R³ = –CN

4.1.1.4.2.8. R¹ = –H, R² = –C(O)X, R³ = –P(O)X₂

4.1.1.4.2.9. R¹ = –H, R² = –C(O)X, R³ = –P⁺X¹X²X³

4.1.1.4.2.10. R¹ = –H, R² = –C(O)X, R³ = (substituted)phenyl

4.1.1.4.2.11. R¹ = –H, R² = –C(O)X, R³ = heterocycle

4.1.1.4.2.12. R¹ = –H, R² = –C(O)X, R³ = functional group,

(substituted) alkyl(alkenyl)

4.1.1.4.3. R¹ = –H, R² = –NO₂, R³ = functional group,

substituted alkyl(alkenyl), cycle

4.1.1.4.4. R¹ = –H, R² = –SX, –S⁺X₂, R³ = functional group, cycle

4.1.1.4.5. R¹ = –H, R² = –S(O)X, R³ = phenyl

4.1.1.4.6. R¹ = –H, R² = –SO₂X, R³ = X

4.1.1.4.6.1. R¹ = –H, R² = –SO₂X, R³ = –SO₂X

4.1.1.4 6.2. R¹ = –H, R² = –SO₂X, R³ = functional group,

substituted alkyl, cycle

4.1.1.4.7. R¹ = –H, R² = –CN, R³ = functional group, substituted alkenyl,

cycle

4.1.1.4.8. R¹ = –H, R² = –P(O), R³ = phenyl

4.1.1.4.9. R¹ = –H, R² = –P(O)X₂, R³ = functional group, substituted alkyl,

cycle

4.1.1.4.10. R¹ = –H, R² = –P(S), R³ = phenyl

4.1.1.4.11. R¹ = –H, R² = –P(S)X₂, R³ = functional group, phenyl

4.1.1.4.12. R¹ = –H, R² = –PPh₂, R³ = functional group, (substituted)phenyl

4.1.1.4.13. R¹ = –H, R² = –N(P⁺Ph₃)X^.Br^-, R³ = functional group,

(substituted)phenyl

4.1.1.4.14. R¹ = –H, R² = (substituted)phenyl , R³ = functional group,

substituted alkyl(alkenyl), cycle

4.1.1.5. R¹ = alkyl, R² = X, R³ = X’

4.1.1.5.1. R¹ = alkyl, R² = alkyl, alkenyl, cycle, R³ = –NO₂

4.1.1.5.2. R¹ = alkyl, R² = alkyl, R³ = functional group, cycle

4.1.1.5.3. R¹ = alkyl, R² = halogen, R³ = –NO₂

4.1.1.5.4. R¹ = alkyl, R² = –OX, R³ = heterocycle

4.1.1.5.5. R¹ = alkyl, alkenyl, R² = –C(O)X, R³ = functional group,

substituted alkyl, cycle

4.1.1.5.6. R¹ = alkyl, R² = –NO₂, R³ = functional group, (substituted)phenyl

4.1.1.5.7. R¹ = alkyl, R² = –SO₂X, R³ = functional group, phenyl

4.1.1.5.8. R¹ = alkyl, R² = –CN, R³ = functional group, (substituted)phenyl

4.1.1.5.9. R¹ = alkyl, R² = phenyl, R³ = phenyl

4.1.1.6. R¹ = functional group, R² = X, R³ = X’

4.1.1.6.1. R¹ = halogen, R² = halogen, R³ = functional group

4.1.1.6.2. R¹ = halogen, R² = –C(O)X, R³ = –NO₂

4.1.1.6.3. R¹ = halogen, R² = –C(O)X, R³ = functional group

4.1.1.6.4. R¹ = halogen, R² = –NO₂, R³ = functional group, substituted alkyl,

substituted phenyl

4.1.1.6.5. R¹ = halogen, R² = –SO₂X, R³ = functional group

4.1.1.6.6. R¹ = halogen, R² = –CN, R³ = functional group

4.1.1.6.7. R¹ = –C(O)X, R² = –C(O)X, R³ = functional group,

substituted alkyl, cycle

4.1.1.6.8. R¹ = –C(O)X, R² = –CN, R³ = functional group,

substituted alkenyl, cycle

4.1.1.6.9. R¹ = –C(O)X, R² = X, R³ = X

(X = functional group, substituted alkyl, cycle)

4.1.1.6.10. R¹ = –C(S)X, R² = –SO₂X, R³ = –CN

4.1.1.6.11. R¹ = –NO₂, R² = –NO₂, R³ = functional group,

substituted alkyl, cycle

4.1.1.6.12. R¹ = –SX, R² = X’, R³ = X’ (X’ = functional group, phenyl)

4.1.1.6.13. R¹ = –SX, R² = X’, R³ = X’ (X’ = phenyl)

4.1.1.6.14. R¹ = –SO₂X, R² = X’, R³ = X’ (X’ = functional group,

substituted alkyl, substituted phenyl)

4.1.1.6.15. R¹ = –CN, R² = –CN, R³ = functional group, substituted

alkyl(alkenyl), substituted phenyl

4.1.1.6.16. R¹ = –CN, R² = substituted phenyl, R³ = functional group, cycle

4.1.1.6.17. R¹ = –CN, R² = X, R³ = X (X = functional group, cycle)

4.1.1.6.18. R¹ = –P(O)X₂, R² = X’, R³ = X’ (X’ = functional group, cycle)

4.1.1.6.19. R¹ = –P(S)X₂, R² = X’, R³ = X’ (X’ = phenyl)

4.1.1.6.20. R¹ = –Ph, R² = Ph, R³ = X (X’ = functional group,

substituted alkenyl, cycle)

4.1.2. R¹COCH=CR²R³

4.1.2.1. R¹COCH=C(OH)R²

4.1.2.2. R¹COCH=C(SH)R²

4.1.2.3. R¹COCH=C(NH₂)R²

4.1.2.4. R¹COCH=C(R²)₂

4.1.3. RC#CH

4.1.4. HCN

4.2. Cyclic CH-acids

4.2.1. Nonaromatic cyclic compounds

4.2.1.1. Carbocyclic compounds

4.2.1.1.1. Monocyclic compounds

4.2.1.1.2. Polycyclic compounds

4.2.1.2. Heterocyclic compounds

4.2.1.2.1. Monocyclic compounds

4.2.1.2.2. Polycyclic compounds

4.2.1.3. Oxycarbocyclic compounds (Carbocyclic compounds contained CO-group)

4.2.1.4. Oxyheterocyclic compounds (Heterocyclic compounds contained CO-group)

4.2.2. Aromatic carbocyclic compounds

4.2.3. Aromatic heterocyclic compounds