4. DISSOCIATION OF CH-ACIDS

 

 

4.1. Aliphatic acids

4.1.1.           R1R2R3CH

4.1.1.1. R1 = H, R2 = H, R3 = X

4.1.1.1.1. R1 = H, R2 = H, R3 = H, alkyl, alkenyl

4.1.1.1.2. R1 = H, R2 = H, R3 = C(O)X

4.1.1.1.3. R1 = H, R2 = H, R3 = functional group, substituted alkyl or

alkenyl

4.1.1.1.4. R1 = H, R2 = H, R3 = phenyl or substituted phenyl

4.1.1.1.5. R1 = H, R2 = H, R3 = heterocycle

4.1.1.2. R1 = H, R2 = alkyl, alkenyl, cycloalkyl, R3 = X

4.1.1.2.1. R1 = H, R2 = alkyl, R3 = alkyl

4.1.1.2.2. R1 = H, R2 = alkyl, R3 = C(O)X

4.1.1.2.3. R1 = H, R2 = alkyl, alkenyl, cycloalkyl, R3 = NO2

4.1.1.2.4. R1 = H, R2 = alkyl R3 = functional group, (substituted) phenyl,

heterocycle

4.1.1.3. R1 = H, R2 ,R3 = alkyl substituted by functional group

4.1.1.4. R1 = H, R2 = functional group, R3 = X

4.1.1.4.1. R1 = H, R2 = halogen, R3 = functional group, (substituted) phenyl

4.1.1.4.2. R1 = H, R2 = C(O)X, R3 = X

4.1.1.4.2.1. R1 = H, R2 , R3 = C(O)X

4.1.1.4.2.1.1. XC(O)CH2C(O)H

4.1.1.4.2.1.2. XC(O)CH2C(O)Me

4.1.1.4.2.1.3. XC(O)CH2C(O)X

4.1.1.4.2.1.4. XC(O)CH2C(O)OX

4.1.1.4.2.1.5. XC(O)CH2C(O)X (X = substituted alkyl)

4.1.1.4.2.1.6. XC(O)CH2C(O)X (X = substituted phenyl)

4.1.1.4.2.1.7. XC(O)CH2C(O)X (X, X = heterocycle)

4.1.1.4.2.2. R1 = H, R2 = C(O)X, R3 = C(S)X

4.1.1.4.2.3. R1 = H, R2 = C(O)X, R3 = NO2

4.1.1.4.2.4. R1 = H, R2 = C(O)X, R3 = SX, S+X2

4.1.1.4.2.5. R1 = H, R2 = C(O)X, R3 = S(O)X

4.1.1.4.2.6. R1 = H, R2 = C(O)X, R3 = SO2X

4.1.1.4.2.7. R1 = H, R2 = C(O)X, R3 = CN

4.1.1.4.2.8. R1 = H, R2 = C(O)X, R3 = P(O)X2

4.1.1.4.2.9. R1 = H, R2 = C(O)X, R3 = P+X1X2X3

4.1.1.4.2.10. R1 = H, R2 = C(O)X, R3 = (substituted)phenyl

4.1.1.4.2.11. R1 = H, R2 = C(O)X, R3 = heterocycle

4.1.1.4.2.12. R1 = H, R2 = C(O)X, R3 = functional group,

(substituted) alkyl(alkenyl)

4.1.1.4.3. R1 = H, R2 = NO2, R3 = functional group,

substituted alkyl(alkenyl), cycle

4.1.1.4.4. R1 = H, R2 = SX, S+X2, R3 = functional group, cycle

4.1.1.4.5. R1 = H, R2 = S(O)X, R3 = phenyl

4.1.1.4.6. R1 = H, R2 = SO2X, R3 = X

4.1.1.4.6.1. R1 = H, R2 = SO2X, R3 = SO2X

4.1.1.4 6.2. R1 = H, R2 = SO2X, R3 = functional group,

substituted alkyl, cycle

4.1.1.4.7. R1 = H, R2 = CN, R3 = functional group, substituted alkenyl,

cycle

4.1.1.4.8. R1 = H, R2 = P(O), R3 = phenyl

4.1.1.4.9. R1 = H, R2 = P(O)X2, R3 = functional group, substituted alkyl,

cycle

4.1.1.4.10. R1 = H, R2 = P(S), R3 = phenyl

4.1.1.4.11. R1 = H, R2 = P(S)X2, R3 = functional group, phenyl

4.1.1.4.12. R1 = H, R2 = PPh2, R3 = functional group, (substituted)phenyl

4.1.1.4.13. R1 = H, R2 = N(P+Ph3)X.Br-, R3 = functional group,

(substituted)phenyl

4.1.1.4.14. R1 = H, R2 = (substituted)phenyl , R3 = functional group,

substituted alkyl(alkenyl), cycle

4.1.1.5. R1 = alkyl, R2 = X, R3 = X

4.1.1.5.1. R1 = alkyl, R2 = alkyl, alkenyl, cycle, R3 = NO2

4.1.1.5.2. R1 = alkyl, R2 = alkyl, R3 = functional group, cycle

4.1.1.5.3. R1 = alkyl, R2 = halogen, R3 = NO2

4.1.1.5.4. R1 = alkyl, R2 = OX, R3 = heterocycle

4.1.1.5.5. R1 = alkyl, alkenyl, R2 = C(O)X, R3 = functional group,

substituted alkyl, cycle

4.1.1.5.6. R1 = alkyl, R2 = NO2, R3 = functional group, (substituted)phenyl

4.1.1.5.7. R1 = alkyl, R2 = SO2X, R3 = functional group, phenyl

4.1.1.5.8. R1 = alkyl, R2 = CN, R3 = functional group, (substituted)phenyl

4.1.1.5.9. R1 = alkyl, R2 = phenyl, R3 = phenyl

4.1.1.6. R1 = functional group, R2 = X, R3 = X

4.1.1.6.1. R1 = halogen, R2 = halogen, R3 = functional group

4.1.1.6.2. R1 = halogen, R2 = C(O)X, R3 = NO2

4.1.1.6.3. R1 = halogen, R2 = C(O)X, R3 = functional group

4.1.1.6.4. R1 = halogen, R2 = NO2, R3 = functional group, substituted alkyl,

substituted phenyl

4.1.1.6.5. R1 = halogen, R2 = SO2X, R3 = functional group

4.1.1.6.6. R1 = halogen, R2 = CN, R3 = functional group

4.1.1.6.7. R1 = C(O)X, R2 = C(O)X, R3 = functional group,

substituted alkyl, cycle

4.1.1.6.8. R1 = C(O)X, R2 = CN, R3 = functional group,

substituted alkenyl, cycle

4.1.1.6.9. R1 = C(O)X, R2 = X, R3 = X

(X = functional group, substituted alkyl, cycle)

4.1.1.6.10. R1 = C(S)X, R2 = SO2X, R3 = CN

4.1.1.6.11. R1 = NO2, R2 = NO2, R3 = functional group,

substituted alkyl, cycle

4.1.1.6.12. R1 = SX, R2 = X, R3 = X (X = functional group, phenyl)

4.1.1.6.13. R1 = SX, R2 = X, R3 = X (X = phenyl)

4.1.1.6.14. R1 = SO2X, R2 = X, R3 = X (X = functional group,

substituted alkyl, substituted phenyl)

4.1.1.6.15. R1 = CN, R2 = CN, R3 = functional group, substituted

alkyl(alkenyl), substituted phenyl

4.1.1.6.16. R1 = CN, R2 = substituted phenyl, R3 = functional group, cycle

4.1.1.6.17. R1 = CN, R2 = X, R3 = X (X = functional group, cycle)

4.1.1.6.18. R1 = P(O)X2, R2 = X, R3 = X (X = functional group, cycle)

4.1.1.6.19. R1 = P(S)X2, R2 = X, R3 = X (X = phenyl)

4.1.1.6.20. R1 = Ph, R2 = Ph, R3 = X (X = functional group,

substituted alkenyl, cycle)

 

4.1.2. R1COCH=CR2R3

4.1.2.1. R1COCH=C(OH)R2

4.1.2.2. R1COCH=C(SH)R2

4.1.2.3. R1COCH=C(NH2)R2

4.1.2.4. R1COCH=C(R2)2

 

4.1.3. RC#CH

4.1.4. HCN

 

4.2. Cyclic CH-acids

4.2.1. Nonaromatic cyclic compounds

4.2.1.1. Carbocyclic compounds

4.2.1.1.1. Monocyclic compounds

4.2.1.1.2. Polycyclic compounds

 

4.2.1.2. Heterocyclic compounds

4.2.1.2.1. Monocyclic compounds

4.2.1.2.2. Polycyclic compounds

 

4.2.1.3. Oxycarbocyclic compounds (Carbocyclic compounds contained CO-group)

4.2.1.4. Oxyheterocyclic compounds (Heterocyclic compounds contained CO-group)

 

4.2.2. Aromatic carbocyclic compounds

4.2.3. Aromatic heterocyclic compounds